Thanks for your suggestions, I have managed to take myself off the blog as admin by removing myself in the Site Admin > Options > Administration Settings > Site Admins section, then logging in as the other admin and deleting myself as a user, however this meant I couldn't admin any of the sites!
I managed to log in as a different admin and return myself as an admin of the main site (in Site Admin > Options > Administration Settings > Site Admins again), however, now the blog that I deleted myself from is not showing up in the BuddyPress directory
I'm obviously doing something wrong somewhere, but not sure what it is.
This is the main site
http://theotherplaceportal.net/
And this is the one I removed myself as admin from
http://theotherplaceportal.net/clears/